2015 Fiscal Year Final Research Report
Characterization and reactivity of nickel(IV) and copper(IV) complexes and their oxidation state equivalents
| Project/Area Number |
25410060
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Ibaraki University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Keywords | 酸化 / 銅(IV) / ニッケル(IV) / フェノキシルラジカル / 酸化数 |
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| Outline of Final Research Achievements |
It is well-known that the metal ion can be obtained by oxidation of elemental metal. For example, copper(II) ion showing the blue color is formed by the oxidation of copper metal. The highest valence state of copper ion can be considered to be +IV state in general. However formation of the highest valence state of the metal ions are quite difficult due to their instability, and therefore detailed properties of the highest valence state metal complexes are still unclear. In this project, determination of the detailed electronic structures of the highest oxidation state of metal complexes, especially copper(IV) and nickel(IV) complexes as formal oxidation number with diphenolate salen ligand, has been attempted.
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| Free Research Field |
無機化学
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