2015 Fiscal Year Final Research Report
Synthesis and Reactivity of Dinuclear Complexes Supported by Linear Tetraphosphine Ligands
| Project/Area Number |
25410069
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nara Women's University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
Tanase Tomoaki 奈良女子大学, 自然科学系, 教授 (50207156)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Keywords | 複核錯体 / 多核錯体 / 四座ホスフィン / 協同効果 / ロジウム / イリジウム / 銅 |
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| Outline of Final Research Achievements |
With an aim to develop new reaction promoted by cooperative effects from two proximate metal centers that would not be established by single metal center, synthesis and reactivities of dinuclear complexes supported by linear tetraphosphine dpmppp ligand were investigated. The aromatic C-H bond activation at dinuclear iridium complexes is assumed to proceed through a two-metal-cooperative pathway switching metal-to metal dative interactions on and off based on X-ray analysis and theoretical calculations.
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| Free Research Field |
有機金属化学
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