2015 Fiscal Year Final Research Report
Self-Assembly of Broxine Cages from Diboronic Acids
| Project/Area Number |
25410087
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Tokyo University of Science (2015)
Tokyo Institute of Technology (2013-2014) |
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Principal Investigator |
Ono Kosuke 東京理科大学, 理学部, 助教 (30579313)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Keywords | 動的共有結合 / かご状分子 / ボロキシン形成反応 |
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| Outline of Final Research Achievements |
By use of the rationally designed unit and dynamic covalent bonds, we aimed the realization of the self-assembly of nm-sized covalent bond cage. Boroxines, trimeric six-membered-ring compounds, are known to be formed reversibly by the dehydration of three molecules of boronic acid. Utilizing this reversible trimerization of boronic acids, the series of boroxine cages 3-mer , 6-mer , and 12-mer were successfully constructed from rationally designed diboronic acids whose bond angles between two C－ B bonds are 60° , 84° , and 117° , respectively.
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| Free Research Field |
超分子化学
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