2015 Fiscal Year Final Research Report
Preparation of porous molecular crystals as nano-materials fabrication templates
| Project/Area Number |
25410092
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Shizuoka University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
KOKADO Satoshi 静岡大学, 工学部, 准教授 (50377719)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Keywords | 有機結晶作製法 / 多孔質 / ナノ構造体 / 配向制御 |
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| Outline of Final Research Achievements |
Fabrication of nano-magnets on several substrates is an attractive field because of their potential use for high-density information storage. Control of the position and distance between nano-magnets is one of the remaining subjects of this field. Our approach to overcome this subject is arranging nano-magnets in crystal using various templates with desired morphology to direct formation of the magnets. Tetrathiafulvalenoquinone-1,3-dithiolemethide derivatives are one of the good candidate for constructing such templates. Because tetrathiafulvalenoquinone-1,3-dithiolemethide derivatives often form porous structures in their crystals and capture inorganic anions. But the size of the porous structures was not enough to capture molecular based magnets or magnetic metal aggregations. In order to enlarge the size of porous structures, we examined molecular arrangements of various methoxycarbonyl substituted tetrathiafulvalenoquinone-1,3-dithiolemethide derivatives.
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| Free Research Field |
材料有機化学
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