2015 Fiscal Year Final Research Report
Synthesis of New Heterobuckybowls
| Project/Area Number |
25410124
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Synthetic chemistry
|
|---|
| Research Institution | Institute for Molecular Science |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2013-04-01 – 2016-03-31
|
| Keywords | バッキーボウル / ヘテロバッキーボウル / おわん型 |
|---|
| Outline of Final Research Achievements |
We succeeded to synthesize a new heterobuckybowl, bow-shaped heteroatom-containing aromatic compound, possessing two neighboring nitrogen atoms in the bowl skeleton. It was revealed that the molecule possesses bowl and twist structures in the neutral state, a shallower bowl structure in the one-electron oxidized state, and a planar structure in the two-electron oxidized state. Since the molecule is reversibly oxidized and reduced, the structure can be changed an controlled between the curved and planar structures by transfer of electrons.
|
| Free Research Field |
有機合成化学
|
