2015 Fiscal Year Final Research Report
Immobilization of crystalline nano-porous structures on the surface of solid materials
| Project/Area Number |
25420719
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic materials/Physical properties
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| Research Institution | Osaka Institute of Technology |
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Principal Investigator |
NOMURA Ryoki 大阪工業大学, 工学部, 教授 (00156233)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Keywords | 柔軟な多孔性配位高分子 / アミノ酸骨格 / 相補的水素結合 / ジチオカーバマート錯体 / ポリビニルピリジン / ポリビニルピロリドン / 無機／有機複合体 |
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| Outline of Final Research Achievements |
Zinc(II) dithiocarbamate complexes having terminal carboxyl moieties which were derived from amino acids behave as a bridging ligand, and can give a novel porous coordination polymer with flexible structure from the reaction with zinc(II) or nickel(II) ions in solution.
Further, novel porous inorganic/organic hybrids can be obtained from the reactions of these zinc complexes with polymers possessing hydrogen acceptors such as polyvinylpyridine or polyvinylpyrrolidone through intermolecular hydrogen bonding. It is also found that crystals of the complexes can be grown onto the surface of such polymers.
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| Free Research Field |
錯体化学
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