2015 Fiscal Year Final Research Report
Development of new chemical transformation using properties of nitrogen-nitrogen bonds
| Project/Area Number |
25460011
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
|
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| Research Institution | Kanazawa University |
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Principal Investigator |
|
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| Project Period (FY) |
2013-04-01 – 2016-03-31
|
| Keywords | ヒドラジン / 光延反応 / 鉄触媒 / 酸素 / ラジカル / ボラン / ベンザイン |
|---|
| Outline of Final Research Achievements |
The following new reactions and concepts have been developed: (1) Development of catalytic Mitsunobu reaction using azo reagents recyclable by iron-catalyzed aerobic oxidation; (2) Development of new reactions of alfa-halo hydrazones; (3) Development of direct functionalization of aromatic rings using aryl radicals from anilines; (4) Discovery of hydroboration of benzynes.
|
| Free Research Field |
有機合成化学
|
