2016 Fiscal Year Final Research Report
Study on Catalytic Radical Reaction Process
| Project/Area Number |
25460028
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Hyogo University of Health Sciences |
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Principal Investigator |
MIYABE Hideto 兵庫医療大学, 薬学部, 教授 (10289035)
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| Co-Investigator(Kenkyū-buntansha) |
甲谷 繁 兵庫医療大学, 薬学部, 准教授 (00242529)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Keywords | 有機合成 / ラジカル / 光触媒 / 触媒反応 / 還元反応 / 環境調和 |
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| Outline of Final Research Achievements |
Our laboratory developed the method for the sequential construction of carbon-carbon bonds based on the radical reactions using a photocatalyst in aqueous media. The utility of ruthenium catalyst and rhodamine B as water-soluble photocatalysts was confirmed in aqueous-medium radical addition-cyclization-trapping reactions under visible light irradiation. The electron transfer from rhodamine B in the excited state was studied by the fluorescence quenching of rhodamine B. The use of titanium dioxide adsorbing coumarin dyes successfully extended the UV response of titanium dioxide toward visible light region.
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| Free Research Field |
有機化学
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