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2014 Fiscal Year Final Research Report

Construction of stimuli-responsive asymmetric thin film for a micro actuator

Research Project

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Project/Area Number 25600027
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Research InstitutionKumamoto University

Principal Investigator

KUNITAKE Masashi  熊本大学, 自然科学研究科, 教授 (40205109)

Co-Investigator(Kenkyū-buntansha) ITAYA Kingo  東北大学, 多元物質科学研究所, その他 (40125498)
Project Period (FY) 2013-04-01 – 2015-03-31
Keywordsナノ材料 / 高分子構造・物性 / 高分子合成 / 界面反応 / 自己組織化 / エマルション
Outline of Final Research Achievements

As a new class of thermosensitive polymer materials, “Janus” nanofilms were produced by the Cu(I)-catalyzed Huisgen click reaction at water-oil interfaces (interface crick reaction) between thermosensitive polymers and lipophilic or hydrophilic polymers. Because the lipophilic polymer, or hydrophilic polymer and a copper catalyst were present in the oil or aqueous phase, respectively, the crosslinking reaction proceeded only at the phase interface. The thermosensitive “Janus” nanofilms with both hydrophilic and thermosensitive surfaces demonstrated a good performance as an actuater.

Free Research Field

高分子化学

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Published: 2016-06-03  

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