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2015 Fiscal Year Annual Research Report

多層エピ成長による結晶配向転換を用いたCМОSプロセスの革新

Research Project

Project/Area Number 25600091
Research InstitutionTohoku University

Principal Investigator

末光 眞希  東北大学, 電気通信研究所, 教授 (00134057)

Project Period (FY) 2013-04-01 – 2016-03-31
Keywords3C-SiC / ヘテロエピタキシ / CMOS / 断面TEM観察 / RHEED
Outline of Annual Research Achievements

MOSデバイスはこれまでSi(100)基板上に構築されてきた。それはこの面方位においてSi/SiO2の界面準位が最小で、その結果、電子移動度が最大だからである。その一方、Si(100)面の正孔移動度は電子移動度の約30%の低い値しか示さず、このためCMOSではNMOSとPMOSの動作速度を合せるべく、前者をわざと大きく創っており、そのことがCMOSデバイスの更なるスケーリングを阻む一因となっていた。本研究は、申請者らが構築してきた結晶成長技術の最新の成果を組み合わせ、正孔移動度がSi(100)面に比べ2倍以上も高いSi(110)基板上にSi(111)結晶をエピタキシャル成長させるという、これまでにない発想の革新的CMOS技術を提案し、原理的実証を行うことを目的として研究を行っている。
最終年度である2015年度は、前年度に実施した工業的製法であるLPCVD装置を用いてシランを原料とするSiC基板上へのSiエピタキシャル成長を行い、X線回折(XRD)によって3C-SiC(111)/Si(110)上にSi(111)が成長していることを確認した。またこれと並行して、Si(110)基板上3C-SiC(111)回転エピ機構を、前年度に開発したRHEED法を用いて詳細に解析し、回転エピ成長は、SiC成長前に形成するアモルファス状バッファ層をSiC成長温度に昇温加熱する段階で回転エピ核が発生することによって生じることが明らかになった。この知見を基に従来にない高品質の3C-SiC(111)/Si(110)回転エピ膜の成長に成功した。

  • Research Products

    (15 results)

All 2016 2015 Other

All Int'l Joint Research (1 results) Journal Article (6 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 6 results,  Open Access: 2 results,  Acknowledgement Compliant: 3 results) Presentation (8 results) (of which Int'l Joint Research: 6 results,  Invited: 4 results)

  • [Int'l Joint Research] トムスク州立大学(ロシア連邦)

    • Country Name
      RUSSIA FEDERATION
    • Counterpart Institution
      トムスク州立大学
  • [Journal Article] Evaluations of crystal defects of 3C-SiC(-1-1-1) film on Si(110) substrate2016

    • Author(s)
      Shota Sambonsuge, Shun Ito, Sai Jiao, Hiroyuki Nagasawa, Hirokazu Fukidome, Sergey N. Filimonov, and Maki Suemitsu
    • Journal Title

      Phys. Status Solidi A

      Volume: 印刷中 Pages: 印刷中

    • DOI

      10.1002/pssa.201532675

    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] 微量O2添加アニール法によるSi(111)及びSi(100)基板上エピタキシャルグラフェン2015

    • Author(s)
      横山大、今泉京、吹留博一、吉越章隆、寺岡有殿、末光眞希
    • Journal Title

      SPring-8/SACLA利用研究成果集

      Volume: 3 Pages: 356-359

    • Peer Reviewed / Open Access
  • [Journal Article] High quality graphene formation on 3C-SiC/4H-AlN/Si heterostructure2015

    • Author(s)
      Sai Jiao, Yuya Murakami, Hiroyoki Nagasawa, Hirokazu Fukidome, Isao Makabe, Yasunori Tateno, Takashi Nakabayashi, and Maki Suemitsu
    • Journal Title

      Materials Science Forum

      Volume: 806 Pages: 89-93

    • DOI

      10.4028/www.scientific.net/MSF.806.89

    • Peer Reviewed
  • [Journal Article] In Situ SR-XPS Observation of Ni-assisted Low-Temperature Formation of Epitaxial Graphene on 3C-SiC/Si2015

    • Author(s)
      Mika Hasegawa, Kenta Sugawara, Ryota Suto, Shota Sambonsuge, Yuden Teraoka, Akitaka Yoshigoe, Sergey Filimonov, Hirokazu Fukidome, Maki Suemitsu
    • Journal Title

      Nanoscale Research Letters(Nano express)

      Volume: 10 Pages: 421-426

    • DOI

      10.1186/s11671-015-1131-9

    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Controlling Planar Defects in 3C-SiC: Ways to Wake it up as a Practical Semiconductor2015

    • Author(s)
      Hiroyoki Nagasawa, Ramya Gurunathan, Maki Suemitsu
    • Journal Title

      Materials Science Forum

      Volume: 821-823 Pages: 108-114

    • DOI

      10.4028/www.scientific.net/MSF.821-823.108

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Formation of qualified epitaxial graphene on Si substrates using two-step heteroexpitaxy of C-terminated 3C-SiC(-1-1-1) on Si(110)2015

    • Author(s)
      Shota Sambonsuge, Sai Jiao, Hiroyuki Nagasawa, Hirokazu Fukidome, Sergey N. Filimonov, Maki Suemitsu
    • Journal Title

      Diamond & Related Materials

      Volume: 67 Pages: 51-53

    • DOI

      10.1016/j.diamond.2016.02.020

    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Recent Progress in the Epitaxial Graphene Formation on 3C-SiC/Si Substrates2016

    • Author(s)
      Maki Suemitsu
    • Organizer
      2016 MRS Spring Meeting & Exhibit
    • Place of Presentation
      Phoenix Convention Center (Pheonix, AZ, USA)
    • Year and Date
      2016-03-31 – 2016-03-31
    • Int'l Joint Research / Invited
  • [Presentation] Recent progress in epitaxial graphene on bulk and thin film SiC crystals2015

    • Author(s)
      Maki Suemitsu
    • Organizer
      IEFM 2015: International symposium on emerging functional materials
    • Place of Presentation
      Songdo Convensia (Incheon, Korea)
    • Year and Date
      2015-11-06 – 2015-11-06
    • Int'l Joint Research / Invited
  • [Presentation] SiCエピタキシャル成長技術と ポリタイプ積層2015

    • Author(s)
      長澤弘幸
    • Organizer
      第45回結晶成長国内会議(NCCG-45)
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2015-10-20 – 2015-10-20
    • Invited
  • [Presentation] Ni-assisted low-temperature formation of epitaxial graphene on3C-SiC/Si and real-time SR-XPS analysis of its reaction2015

    • Author(s)
      Mika Hasegawa
    • Organizer
      2015 international Conference of Silicon Carbide and Related Materials
    • Place of Presentation
      Congress Center Atahotel Naxos Beach (Giadirni Naxos, Italy)
    • Year and Date
      2015-10-06 – 2015-10-06
    • Int'l Joint Research
  • [Presentation] Epitaxial graphene formation on SiC and on Si substrates2015

    • Author(s)
      Maki Suemitsu
    • Organizer
      PSS 2015: Physical Sciences Symposia-2015
    • Place of Presentation
      Courtyard Marriott (Cambridge, MA, USA)
    • Year and Date
      2015-09-22 – 2015-09-22
    • Int'l Joint Research / Invited
  • [Presentation] Si(110)上3C-SiC(111)薄膜の結晶方位回転成長機構2015

    • Author(s)
      横山大、フィリモノフ セルゲイ、長澤弘幸、吹留博一、末光眞希
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-15 – 2015-09-15
  • [Presentation] Evaluations of crystal defects of 3C-SiC(-1-1-1) film on Si(110) substrate2015

    • Author(s)
      Maki Suemitsu
    • Organizer
      SENM2015: the international conference on Smart Engineering of New Materials
    • Place of Presentation
      Andel's Hotel (Lodz, Poland)
    • Year and Date
      2015-06-25 – 2015-06-25
    • Int'l Joint Research
  • [Presentation] Formation of qualified epitaxial graphene on Si substrates using two-step heteroexpitaxy of C-terminated 3C-SiC(-1-1-1) on Si(110)2015

    • Author(s)
      Maki Suemitsu
    • Organizer
      SENM2015: the international conference on Smart Engineering of New Materials
    • Place of Presentation
      Andel's Hotel (Lodz, Poland)
    • Year and Date
      2015-06-23 – 2015-06-23
    • Int'l Joint Research

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Published: 2017-01-06   Modified: 2022-01-31  

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