• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2015 Fiscal Year Final Research Report

Study on the transition metal complexes bearing a hypervalent silicon ligand and their application to catalytic reactions

Research Project

  • PDF
Project/Area Number 25620024
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

Kano Naokazu  東京大学, 理学(系)研究科(研究院), 准教授 (00302810)

Project Period (FY) 2013-04-01 – 2016-03-31
Keywords14族元素 / 超原子価化合物 / 結合形成 / 高配位化合物
Outline of Final Research Achievements

Transition metal complexes bearing hypervalent silicon ligands were tried in vain to be synthesized for their application to efficient transition metal catalyst. The tin analogues were successfully synthesized. Their structures and properties were revealed. The tin ligand works as the Z-type ligand in these complexes. New types of homonuclear bonding of hypervalent germanium and tin atoms,respectively, were also synthesized and studied.

Free Research Field

典型元素化学

URL: 

Published: 2017-05-10  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi