2014 Fiscal Year Final Research Report
Creation of hydrogen gas production reaction from alcohol catalyzed by an iron complex
| Project/Area Number |
25620048
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka City University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
ITAZAKI Masumi 大阪市立大学, 大学院理学研究科, 講師 (60382032)
KAMEO Hajime 大阪府立大学, 大学院理学系研究科, 助教 (50597218)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Keywords | 脱水素反応 / 鉄錯体触媒 / 水素分子生成 |
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| Outline of Final Research Achievements |
Hydrogen molecule has attracted considerable attention as a clean energy source. Hydrogen transfer reaction in which hydrogen gas produced by the conversion of alcohol to ketone or aldehyde has been widely investigated. In contrast, it is known to be difficult to get hydrogen gas produced in a hydrogen transfer reaction. In this project, we succeeded in the conversion of 2-pyridylalcohol derivatives to the corresponding ketone or aldehyde. As the reaction takes place without sacrificing the hydrogen acceptors, molecular hydrogen gas can be obtained. The highest turnover number achieved was 67,000 which is the world record in the reactions catalyzed by an iron complex.
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| Free Research Field |
有機金属化学
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