Development of semi-conducting organic nanoparticles with electron-transporting property toward creating key materials for organic electronics

2014 Fiscal Year Final Research Report

• Project/Area Number: 25620093
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Polymer chemistry
• Research Institution: Yamagata University
• Principal Investigator: MORI Hideharu 山形大学, 理工学研究科, 教授 (00262600)
• Co-Investigator(Kenkyū-buntansha): NAKABAYASHI Kazuhiro 山形大学, 大学院理工学研究科, 助教 (30613765)
• Project Period (FY): 2013-04-01 – 2015-03-31
• Keywords: 精密ラジカル重合 / コア架橋型微粒子 / 有機半導体 / 架橋反応 / ブロック共重合体 / 自己組織化 / 有機・無機ハイブリッド

Outline of Final Research Achievements

Core cross-linked nanoparticles with electron-transporting cores have been developed by the combination of the synthesis of reactive block copolymers by RAFT polymerization, formation of polymeric nanostructures by self-assembly, and situ-selective cross-coupling reactions. We have successfully synthesized donor-acceptor type nanoparticles by Suzuki coupling reaction, perylene and naphthalene bisimide-based nanoparticles by imidization, thermoresponsive nanoparticles with optoelectronic cores by imine formation, and hybrid nanoparticles using silsesquioxane-based chain transfer agent, respectively.

Free Research Field

高分子化学