2014 Fiscal Year Final Research Report
Exploitation of Artifitial Gas-Hydrate Stabilized in Molecule-based Crystal at Normal Temperature and Pressure
| Project/Area Number |
25620154
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Energy-related chemistry
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| Research Institution | Tokyo University of Science |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
ISODA Kyousuke 東京理科大学, 理学部, 助教 (20568620)
SUZUKI You 東京理科大学, 理学部, ポストドクトラル研究員 (60647395)
SUGAYA Tomoaki 東京理科大学, 総合研究機構, ポストドクトラル研究員 (30633367)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Keywords | 水クラスター / ガスハイドレート / キセノン / 多孔質結晶 / 超分子 / 固体NMR / 金属錯体 / ガス吸蔵 |
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| Outline of Final Research Achievements |
Gas Hydrate such as Metane Hydrate can maintain the framework structure only under the extreme condition at low temperature and high pressure due to a unique ice structure. Wa have found that the molecule-based nanoporous crystal formed from [Ru(Hbim)3]3+ complexes and TMA3-(trimasate) spacer is stabilized a huge hollow water cluster (WNT) in the 1-D nanochannels. First of all, the nanoporous crystal are obtained as THF Hydrate, whose THF molecules can remove under a 50%RH humidity for 1 hour to obtain the hollow water clusters. The hollow WNT cluster can clathrate Xe gases and the absorption can be reversibly release Xe gases at 243 K and 7 atm.
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| Free Research Field |
錯体化学
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