Creation of pseudo liquid phase of perfluoroalkane in the nanospace realizing an innovative gas adsorption at room temperature.

2014 Fiscal Year Final Research Report

• Project/Area Number: 25620187
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Inorganic industrial materials
• Research Institution: Kyoto University
• Principal Investigator: MATSUDA Ryotaro 京都大学, 物質-細胞統合システム拠点, 准教授 (00402959)
• Project Period (FY): 2013-04-01 – 2015-03-31
• Keywords: 多孔性配位高分子 / 金属錯体 / 細孔 / ナノ空間 / 吸着 / MOF

Outline of Final Research Achievements

Porous coordination polymers (PCPs) or metal-organic frameworks (MOFs) assembled from various organic ligands and metal ions/clusters have been fascinating to materials scientists due to their potential applications in gas storage, separation, catalysis, conductivity etc. In this work, we have succeeded in the synthesis of new PCPs having fluorinated nanospace. We found that the fluorinated nanospace showed unusual guest uptake phenomena which provide a new guideline for the design of nanoporous materials showing selective gas adsorption.

Free Research Field

錯体化学