2015 Fiscal Year Final Research Report
Fabrication of chiral metamaterials by metalic meso-helical structure arrays
| Project/Area Number |
25706006
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Partial Multi-year Fund |
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| Research Field |
Nanomaterials chemistry
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| Research Institution | Tohoku University |
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Principal Investigator |
HIGUCHI TAKESHI 東北大学, 多元物質科学研究所, 助教 (50547304)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Keywords | ナノ構造創製 / ミクロ相分離 / らせん / 金属粒子 / クリック反応 |
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| Outline of Final Research Achievements |
In this research, we are aimed at a preparation of metalic meso-helical structure arrays by using helical structures of block copolymers as a templete. To control of handedness of helical structures of block copolymers, the chiral compounds were covalently attached to the chemical junction between first and second polymer segments in the linear triblock terpolymer by click reaction. The helical polymer domains were successfully metalized by complexation reaction and subsequent thermal reduction.
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| Free Research Field |
高分子構造
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