2015 Fiscal Year Final Research Report
Construction of supramolecular multi-ferrocenyl assemblies toward molecular devices using intramolecular charge distributions as information
| Project/Area Number |
25790016
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Nanomaterials chemistry
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| Research Institution | Nara Institute of Science and Technology |
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Principal Investigator |
Tahara Keishiro 奈良先端科学技術大学院大学, 物質創成科学研究科, 助教 (50622297)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Keywords | フェロセン / 超分子 / 分子内電荷移動 |
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| Outline of Final Research Achievements |
Covalent and non-covalent assemblies were constructed from multi-ferrocenyl complexes as building blocks to obtain insight into utilization of intramolecular charge transfer properties for molecular devices. 1',1’’’-Biferrocenediboronic acid was newly synthesized and chemically oxidized to afford a 1D hydrogen-bonded chain of valence-detrapped biferrocenium species in the solid state. A Biferrocene dimer was also prepared as a covalent assembly, exhibiting inter-biferrocenyl interactions derived from electrostatic repulsions in its solution.
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| Free Research Field |
錯体化学
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