2014 Fiscal Year Final Research Report
Synthesis and functionalization of Kumiigeta-type chiral compounds
| Project/Area Number |
25810028
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Seikei University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Keywords | キラリティー / 大環状化合物 / キロプティカル特性 / ビナフチル / 組井桁 |
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| Outline of Final Research Achievements |
We present a series of cyclic structures constructed from obliquely crossing rod segments, which have chirality based on the direction of the rods with respect to the molecular plane. This structure is called ‘Kumiigeta’. The chiral compounds of this type are expected to have novel and useful functions. Kumiigeta-compounds were synthesized using axially chiral binaphthyls and rod type compounds. Conformation and optical properties of them were analyzed by UV-Vis, CD spectra and quantum chemical calculations.
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| Free Research Field |
有機化学
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