2014 Fiscal Year Final Research Report
Fabrication and Physical Properties of Growth-Controlled Metal-Organic Framework Thin Films
Project/Area Number |
25810039
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Inorganic chemistry
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Research Institution | Kyoto University |
Principal Investigator |
OTSUBO Kazuya 京都大学, 理学(系)研究科(研究院), 助教 (90601005)
|
Project Period (FY) |
2013-04-01 – 2015-03-31
|
Keywords | 多孔性配位高分子 / 薄膜 / ナノ界面技術 |
Outline of Final Research Achievements |
By using simple layer-by-layer method, crystalline thin film of two-dimensional Hofmann-type metal-organic framework was successfully fabricated. The thin-film obtained shows clear guest adsorption behavior with gate-opening-type structural transformation, which have been revealed by in-situ X-ray studies. Moreover, enlargement of the thin film controlled by the thickness suppresses this dynamic behavior remarkably showing clear crystal downsizing effect.
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Free Research Field |
固体物性化学
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