2014 Fiscal Year Final Research Report
| Project/Area Number |
25810050
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
HIRAO Yasukazu 大阪大学, 理学(系)研究科(研究院), 助教 (50506392)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Keywords | プロトン共役電子移動 / 有機ラジカル / 水素結合 / 結晶構造 / パイ共役系 |
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| Outline of Final Research Achievements |
This project was focused on the proton coupled electron transfer (PCET) at the hydrogen bond between phenol and phenoxyl radical to apply to a novel electron transfer mechanism at solid state. We tried to aggregate PCET active units and interact each other to construct a network structure. By combining hydrogen bonds with pi-pi stacks, or by the linkage of molecules having two hydrogen-bonding sites, two types of one-dimensional chain structures were successfully obtained. One of the chains gave a proton and an electron exchange at the hydrogen bond, and it can be widely found in solid.
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| Free Research Field |
構造有機化学
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