2014 Fiscal Year Final Research Report
Development of a core-shell type catalyst bearing a mesoporous silica coated silica beads for environmental benign amidation
| Project/Area Number |
25810107
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Green/Environmental chemistry
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| Research Institution | Gifu University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Keywords | メソポーラスシリカ / アミド化反応 / グリーンケミストリー |
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| Outline of Final Research Achievements |
For environmental benign amidation reaction, we have developed a core-shell type catalyst as new mesoporous silica catalyst which is mesoporous silica coated silica beads. The optimization of mesoporous silica revealed that both appropriate density of silanol and pore size trigger the highest catalytic activity for direct amidation reaction. Under various modification conditions of silica beads, it can be succeeded the preparation of silica beads covered by mesoporous silica, assigned by nitrogen adsorption-desorption isotherm and FE-SEM. However, it is observed the partial cracks and unmodified moiety.
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| Free Research Field |
触媒化学
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