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2014 Fiscal Year Final Research Report

Pyrrole-based Novel Functional Molecules

Research Project

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Project/Area Number 25888011
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Functional solid state chemistry
Research InstitutionKyoto University

Principal Investigator

HIGASHINO Tomohiro  京都大学, 工学(系)研究科(研究院), 助教 (90711804)

Project Period (FY) 2013-08-30 – 2015-03-31
Keywords有機化学 / ピロール / 典型元素化学 / ヘテロール / 機能性材料
Outline of Final Research Achievements

In this research, we developed novel pyrrole-based pi-conjugated molecules with main group elements. We synthesized the bipyrrole as a key intermediate. In the next step, we attmpted to introduce the main group elements into bipyrroles. While we could not obtained compound with nitrogen atom, we succeeded in the synthesis of compounds containing sulfur, phosphorus, and silicon atoms. We evaluated their properties and revealed that they are the rare examples of radialene-like molecules.

Free Research Field

有機化学

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Published: 2016-06-03  

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