2014 Fiscal Year Final Research Report
Development of small molecule activation systems based on the photoexcitation of metal complexes
| Project/Area Number |
25888023
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
YOSHIDA Masaki 北海道大学, 理学(系)研究科(研究院), 助教 (20712293)
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| Project Period (FY) |
2013-08-30 – 2015-03-31
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| Keywords | 錯体化学 / 電子状態 / 触媒・化学プロセス |
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| Outline of Final Research Achievements |
In this work, we tried to investigate the development of oxidation and reduction systems under mild conditions. As a result, we have discovered (i) new highly-active water oxidation catalysts based on the construction of the heterometallic reaction center (ii) novel oxo-bridged dinuclear ruthenium complex exhibiting alcohol oxidation activity under mild conditions (iii) photo-induced hydrogen evolution using 3d transition-metal complexes.
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| Free Research Field |
錯体化学
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