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2016 Fiscal Year Annual Research Report

Origin and crystallization mechanism of polycrystalline diamonds in the deep Earth

Research Project

Project/Area Number 26287138
Research InstitutionEhime University

Principal Investigator

大藤 弘明  愛媛大学, 地球深部ダイナミクス研究センター, 教授 (80403864)

Co-Investigator(Kenkyū-buntansha) 井上 徹  愛媛大学, 地球深部ダイナミクス研究センター, 教授 (00291500)
鍵 裕之  東京大学, 理学(系)研究科(研究院), 教授 (70233666)
Project Period (FY) 2014-04-01 – 2017-03-31
Keywords多結晶ダイヤモンド / カーボナード / 包有物
Outline of Annual Research Achievements

前年度の成果を踏まえて,多結晶ダイヤモンド,カーボナード中に観察される包有物の記載,分析を進めた.外部からの異物や汚染物質の混入や機械研磨時の物理的なダメージの影響を取り除くため,イオンビーム(クロスセクションポリッシャおよびFIB)を用いた試料断面を作成し,研磨面をまずはFE-SEMを用いて詳細に観察した.その結果,カーボナード中に含まれる包有物は,結晶粒内に含まれる1次包有物と粒界やクラックを充填する2次包有物に大分されることが分かった.
1次包有物の多くは直径数百nmと極めて微細で,内部は鉱物相によって充填されていた.FIBを用いて薄膜を作成し,透過電顕下で観察したところ,すべての1次包有物は負晶として存在し,その内部にはガーネット(メジャーライト)やフェンジャイト,ルチル,アパタイトなどの複数の析出相を含んでいることが明らかとなった.これらの産状から,そららの包有物はケイ酸塩や多くの金属イオンに飽和した流体包有物としてカーボナードの形成時にダイヤモンド結晶内部に取り込まれたものと考えられる.鉱物組み合わせから判断して,これらの包有物(流体相)は沈み込んだ海洋地殻物質に起源をもつ可能性が高く,これまで成因や生成環境が不明であったカーボナードが確かに地球深部で生成したことを強く裏付けるものである.なお,メジャーライト中のSi濃度を用いた検討では,カーボナードの生成震度は上部マントル下部からマントル遷移層上部にかけてと推測される.
一方,二次包有物についても詳細な記載を行い,ルチルやゲーサイト,カオリナイトの他,フローレンサイトなどの特徴的な鉱物相で構成される包有物もあり,カーボナードがその形成後,地殻への上昇過程に複数の流体と接触し,部分的に交代・変質作用を被っていることが分かった.現在,これらの結果について論文にまとめている.

Research Progress Status

28年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

28年度が最終年度であるため、記入しない。

Causes of Carryover

28年度が最終年度であるため、記入しない。

Expenditure Plan for Carryover Budget

28年度が最終年度であるため、記入しない。

  • Research Products

    (37 results)

All 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (19 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 19 results,  Open Access: 4 results,  Acknowledgement Compliant: 1 results) Presentation (16 results) (of which Int'l Joint Research: 9 results,  Invited: 7 results)

  • [Int'l Joint Research] ロシア科学アカデミー(ロシア連邦)

    • Country Name
      RUSSIA FEDERATION
    • Counterpart Institution
      ロシア科学アカデミー
  • [Int'l Joint Research] 米国宝石学会(米国)

    • Country Name
      U.S.A.
    • Counterpart Institution
      米国宝石学会
  • [Journal Article] ynthesis of coarse-grain-dispersed nano-polycrystalline cubic boron nitride by direct transformation under ultrahigh pressure2017

    • Author(s)
      Y. Ichida, H. Ohfuji, T. Irifune, T. Kunimoto, Y. Kojima, T. Shinmei
    • Journal Title

      Diamond and Related Materials

      Volume: 印刷中 Pages: 印刷中

    • Peer Reviewed
  • [Journal Article] Water-bearing, high-pressure Ca-silicates2017

    • Author(s)
      P. Nemeth, K. Leinenweber, H. Ohfuji, T. Groy, K.J. Domanik, I.J. Kovacs, J.S. Kovacs, P.R. Buseck
    • Journal Title

      Earth and Planetary Science Letters

      Volume: 印刷中 Pages: 印刷中

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Precipitates within olivine phenocrysts in oxidized andesitic scoria from Kasayama volcano, Hagi, Yamaguchi Prefecture2017

    • Author(s)
      T. Ejima, M. Yamada, M. Akasaka, H. Ohfuji, T. Kon, M. Nagashima, Y. Nakamuta
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 印刷中 Pages: 印刷中

    • Peer Reviewed
  • [Journal Article] Melting temperatures of MgO under high pressure by micro-texture analysis2017

    • Author(s)
      T. Kimura, H. Ohfuji, M. Nishi, T. Irifune
    • Journal Title

      Nature Communications

      Volume: 印刷中 Pages: 印刷中

    • Peer Reviewed / Open Access
  • [Journal Article] Transition mechanism of sH to filled-ice Ih structure of methane hydrate under fixed pressure condition2017

    • Author(s)
      H. Kadobayashi, H. Hirai, H. Ohfuji, Y. Kojima, Y. Ohishi, N. Hirao, M. Ohtake, Y. Yamamoto
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 印刷中 Pages: 印刷中

    • Peer Reviewed
  • [Journal Article] Melting relations in the MgO-MgSiO3 system up to 70 GPa2017

    • Author(s)
      S. Ohnishi, T. Kuwayama, T. Inoue
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 印刷中 Pages: 印刷中

    • DOI

      10.1007/s00269-017-0871-8

    • Peer Reviewed
  • [Journal Article] Mineralogical and crystallographic features of polycrystalline yakutite diamond2017

    • Author(s)
      H. Ohfuji, M. Nakaya, A.P. Yelisseyev, V.P. Afanasiev, K.D. Litasov
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 112 Pages: 46-51

    • DOI

      10.2465/jmps.160719g

    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Transparent polycrystalline cubic silicon nitride2017

    • Author(s)
      N. Nishiyama, R. Ishikawa, H. Ohfuji, H. Marquardt, A. Kurnosov, T. Taniguchi, B.-N. Kim, H. Yoshida, A. Masuno, J. Bednarcik, E. Kulik, Y. Ikuhara, F. Wakai, T. Irifune
    • Journal Title

      Scientific Reports

      Volume: 7 Pages: 44755

    • DOI

      10.1038/srep44755

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Stability region of K0.2Na0.8AlSi3O8 hollandite at 22 GPa and 2273 K2017

    • Author(s)
      Y. Zhou, T. Irifune, H. Ohfuji, T. Shinmei, W. Du
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 44 Pages: 32-42

    • DOI

      10.1007/s00269-016-0834-5

    • Peer Reviewed
  • [Journal Article] Stability field of phase Egg, AlSiO3OH at high pressure and high temperature: possible water reservoir in mantle transition zone2017

    • Author(s)
      K. Fukuyama, E. Ohtani, Y. Shibazaki, H. Kagi, A. Suzuki
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 112 Pages: 31-35

    • DOI

      10.2465/jmps.160719e

    • Peer Reviewed
  • [Journal Article] Detection of increased heating and estimation of coseismic shear stress from Raman spectra of carbonaceous material in pseudotachylytes2017

    • Author(s)
      K. Ito, K. Ujiie, H. Kagi
    • Journal Title

      Geophysical Research Letters

      Volume: 44 Pages: 1749-1757

    • DOI

      10.1002/2016GL072457

    • Peer Reviewed
  • [Journal Article] Structural incorporation of MgCl2 into ice VII at room temperature2017

    • Author(s)
      M. Watanabe, K. Komatsu, F. Noritake, H. Kagi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Pages: 05FB03

    • DOI

      10.7567/JJAP.56.05FB03

    • Peer Reviewed / Open Access
  • [Journal Article] Pressure-induced nano-crystallization of silicate garnets from glass2016

    • Author(s)
      T. Irifune, K. Kawakami, T. Arimoto, H. Ohfuji, T. Kunimoto, T. Shinmei
    • Journal Title

      Nature Communications

      Volume: 7 Pages: 13753

    • DOI

      10.1038/ncomms13753

    • Peer Reviewed / Open Access
  • [Journal Article] Stability and partial oligomerization of naphthalene under high pressure at room temperature2016

    • Author(s)
      A. Shinozaki, K. Mimura, T. Nishida, T. Inoue, S. Nakano and H. Kagi
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 662 Pages: 263-267

    • DOI

      10.1016/j.cplett.2016.09.042

    • Peer Reviewed
  • [Journal Article] Micro- and nano-inclusions in a superdeep diamond from São Luiz, Brazil2016

    • Author(s)
      H. Kagi, D.A. Zedgenizov, H. Ohfuji, H. Ishibashi
    • Journal Title

      Geochemistry International

      Volume: 54 Pages: 882-889

    • DOI

      10.1134/S0016702916100062

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Relationships between textural and photoluminescence spectral features of carbonado (natural polycrystalline diamond) and implications for its origin2016

    • Author(s)
      H. Ishibashi, H. Kagi, S. Odake, H. Ohfuji, H. Kitawaki
    • Journal Title

      Geochemistry International

      Volume: 54 Pages: 882-889

    • DOI

      10.1134/S0016702916100050

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Phase relation of CaSO4 at high pressure and high temperature up to 90 GPa and 2300 K2016

    • Author(s)
      T. Fujii, H. Ohfuji, T. Inoue
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 43 Pages: 353-361

    • DOI

      10.1007/s00269-016-0799-4

    • Peer Reviewed
  • [Journal Article] The mineralogy of Ca-rich inclusions in sublithospheric diamonds2016

    • Author(s)
      D.A. Zedgenizov, A.L. Ragozin, V.V. Kalinina, H. Kagi
    • Journal Title

      Geochemistry International

      Volume: 54 Pages: 890-900

    • DOI

      10.1134/S0016702916100116

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Pressure-induced freeze concentration of alanine aqueous solution as a novel field of chemical reaction2016

    • Author(s)
      S. Takahashi, H. Kagi, C. Fujimoto, A. Shinozaki, H. Gotou, T. Nishida, K. Mimura
    • Journal Title

      Chemistry Letters

      Volume: 46 Pages: -

    • DOI

      10.1246/cl.160992

    • Peer Reviewed
  • [Presentation] Synthesis and properties of ultrahard, transparent nanopolycrystalline diamond2016

    • Author(s)
      H. Ohfuji and T. Irifune
    • Organizer
      12th Laser Ceramics Symposium
    • Place of Presentation
      Saint Louis, France
    • Year and Date
      2016-11-30
    • Int'l Joint Research / Invited
  • [Presentation] Pressure-induced olygomerization of L-alanine: prebiologic peptide formation in icy planets2016

    • Author(s)
      H. Kagi, C. Fujimoto, S. Takahashi, K. Komatsu and A. Shinozaki
    • Organizer
      2016 International Conference on the Earth’s Deep Interior
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2016-11-06
    • Int'l Joint Research / Invited
  • [Presentation] 高圧下におけるAlに富むブリッジマナイトの弾性波速度測定2016

    • Author(s)
      井上徹,Greaux Steeve,野田昌道,柿澤翔,肥後祐司,丹下慶範
    • Organizer
      第57回高圧討論会
    • Place of Presentation
      筑波大学(茨城県・つくば市)
    • Year and Date
      2016-10-26 – 2016-10-28
  • [Presentation] 高温高圧,C-H-O流体存在下におけるMgSiO3の分解2016

    • Author(s)
      大藤弘明,井川舜太,門林宏和,木村友亮
    • Organizer
      日本鉱物科学会2016年年会
    • Place of Presentation
      金沢大学(石川県・金沢市)
    • Year and Date
      2016-09-25
  • [Presentation] Alに富む無水及び含水ブリッジマナイトの弾性波速度測定2016

    • Author(s)
      井上徹,Greaux Steeve,野田昌道,柿澤翔,肥後祐司,丹下慶範
    • Organizer
      日本鉱物科学会2016年年会
    • Place of Presentation
      金沢大学(石川県・金沢市)
    • Year and Date
      2016-09-23 – 2016-09-25
  • [Presentation] Successful synthesis of pure, super-hard carbon nitride at high pressure and high temperature2016

    • Author(s)
      H. Ohfuji
    • Organizer
      8th International Workshop on Spinel Nitrides and Related Materials
    • Place of Presentation
      Rudesheim, Germany
    • Year and Date
      2016-09-08
    • Int'l Joint Research
  • [Presentation] Water storage capacity in the lower mantle2016

    • Author(s)
      T. Inoue
    • Organizer
      International Symposium "Advances in High-pressure Research-III: Towards Geodynamic Implications-2016"
    • Place of Presentation
      Novosibirsk, Russia
    • Year and Date
      2016-08-29 – 2016-08-30
    • Int'l Joint Research
  • [Presentation] Diamond formation from magnesite in the presence of C-H-O fluid under high pressure and temperature2016

    • Author(s)
      H. Ohfuji
    • Organizer
      International Symposium "Advances in High-pressure Research-III: Towards Geodynamic Implications-2016"
    • Place of Presentation
      Novosibirsk, Russia
    • Year and Date
      2016-08-29
    • Int'l Joint Research
  • [Presentation] 微細組織から探る鉱物の結晶化プロセス~天然鉱物から世界最硬の人造ダイヤまで~2016

    • Author(s)
      大藤弘明
    • Organizer
      JEOL 2016SEMユーザーズミーティング(大阪)
    • Place of Presentation
      千里ライフサイエンスセンター(大阪府・豊中市)
    • Year and Date
      2016-07-08
    • Invited
  • [Presentation] 微細組織から探る鉱物の結晶化プロセス~天然鉱物から世界最硬の人造ダイヤまで~2016

    • Author(s)
      大藤弘明
    • Organizer
      JEOL 2016SEMユーザーズミーティング(東京)
    • Place of Presentation
      東京大学(東京都・文京区)
    • Year and Date
      2016-07-01
    • Invited
  • [Presentation] Mantle Origin of Natural Polycrystalline Diamond, Carbonado, Inferred from Inclusion Chemistry2016

    • Author(s)
      H. Kagi, N. Shiraishi, H. Sumino, N. Asano, H. Ohfuji, R. Senda and K. Suzuki
    • Organizer
      Goldschmidt 2016
    • Place of Presentation
      パシフィコ横浜(神奈川県・横浜市)
    • Year and Date
      2016-06-29
    • Int'l Joint Research / Invited
  • [Presentation] Diamond formation from magnesite in the presence of C-H-O fluid under high pressure and temperature2016

    • Author(s)
      H. Ohfuji, S. Ikawa and T. Kimura
    • Organizer
      Goldschmidt 2016
    • Place of Presentation
      パシフィコ横浜(神奈川県・横浜市)
    • Year and Date
      2016-06-28
    • Int'l Joint Research
  • [Presentation] Hydrous bridgmanite: Possible water reservior in the lower mantle2016

    • Author(s)
      T. Inoue, S. Kakizawa, K. Fujino, T. Kuribayashi, T. Nagase, S. Greaux, T. Higo, N. Sakamoto, H. Yurimoto, T. Hattori and A. Sano
    • Organizer
      Goldschmidt 2016
    • Place of Presentation
      パシフィコ横浜(神奈川県・横浜市)
    • Year and Date
      2016-06-26 – 2016-07-01
    • Int'l Joint Research
  • [Presentation] Experimental study on the graphite-diamond transformation and its implication for the formation mechanism of natural impact diamonds2016

    • Author(s)
      H. Ohfuji
    • Organizer
      DCO (Deep Carbon Observatory) Symposium
    • Place of Presentation
      パシフィコ横浜(神奈川県・横浜市)
    • Year and Date
      2016-06-26
    • Int'l Joint Research / Invited
  • [Presentation] 多結晶ダイヤモンドYakutiteの鉱物結晶学的特徴とその起源2016

    • Author(s)
      大藤弘明,中谷元祐,Litasov Konstantin, Afanasiev Valentin, Yelisseyev Alexander
    • Organizer
      日本地球惑星科学連合2016年大会
    • Place of Presentation
      幕張メッセ(千葉県・千葉市)
    • Year and Date
      2016-05-25
  • [Presentation] Hydrous bridgmanite: Water storage capacity in the lower mantle2016

    • Author(s)
      井上徹,柿澤翔,藤野清志,栗林貴弘,長瀬敏郎,Greaux, S.,肥後祐司,坂本直哉,圦本尚義,服部高典,佐野亜沙美
    • Organizer
      日本地球惑星科学連合2016年大会
    • Place of Presentation
      幕張メッセ(千葉県・千葉市)
    • Year and Date
      2016-05-22 – 2016-05-26
    • Invited

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Published: 2018-01-16   Modified: 2022-02-16  

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