2017 Fiscal Year Final Research Report
Development of cyclization reaction based on the internal redox reaction which involves C-H activation reaction
| Project/Area Number |
26288053
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Gakushuin University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2018-03-31
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| Keywords | 有機合成化学 / 選択的反応 / 炭素ー水素結合活性化 / 環化反応 / 触媒反応 / internal redox reaction |
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| Outline of Final Research Achievements |
Development of efficient synthetic method leading to the biologically active compounds represents one of the important task of organic chemistry.
We are interested in the internal redox reaction which involves [1,5]-H shift and subsequent cyclization reaction to form cyclized product. This internal redox reaction does not require external oxidatant because both reduction and oxidation took place in the molecule. We have developed domino internal reaction and enantioselective version of the domino reaction.
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| Free Research Field |
有機合成化学
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