2016 Fiscal Year Final Research Report
Control of Highly Dimensional Structure of pi-Conjugated Compounds and Functionalization
| Project/Area Number |
26288093
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic and hybrid materials
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Research Collaborator |
SAEKI Akinori 大阪大学, 大学院工学研究科, 准教授
MURATA Yasujiro 京都大学, 化学研究所, 教授
KAJI Hironori 京都大学, 化学研究所, 教授
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Keywords | π共役 / 有機半導体材料 / 高次元 / 太陽電池 / 円偏光発光 / 近赤外吸収 / ペロブスカイト |
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| Outline of Final Research Achievements |
We developed a series of functional pi-electronic materials using our original pi-skeleton from viewpoints of control of highly dimensional orientation of compound in the solid state. For example, HND-Azulene bearing quasi-planar skeleton and azulene core was demonstrated to exhibit high performance as p-type semiconductor in perovskite solar cells. the cells using HND-Azulene improves the power conversion efficiency by 1.2 times compared to that with standard materials. We also designed and synthesized T-shaped skeleton, which was found to be useful as an electron-accepting unit in D-A materials in organic photovoltaics. Moreover, the expanded quasi-planar skeleton can be used as a key skeleton for CPL materials, which allow the emission color tuning over the whole visible region.
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| Free Research Field |
材料化学
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