2017 Fiscal Year Final Research Report
Development of Various Electric Energy Storage Devices based on Halogen Redox Reactions
Project/Area Number |
26288112
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Partial Multi-year Fund |
Section | 一般 |
Research Field |
Device related chemistry
|
Research Institution | Kansai University |
Principal Investigator |
|
Co-Investigator(Kenkyū-buntansha) |
山縣 雅紀 関西大学, 化学生命工学部, 准教授 (80527119)
|
Project Period (FY) |
2014-04-01 – 2018-03-31
|
Keywords | 電池 / キャパシタ / ハロゲン / 炭素電極 / 蓄電 / マグネシウム負極 / マグネシウム電解液 / マグネシウム空気電池 |
Outline of Final Research Achievements |
We applied halogen (e.g., bromine)-redox systems to charge-storage electrode reactions. Activated carbon was utilized to keep reversible reactions of halogens in its micropores. An electric double layer capacitor (EDLC) was designed with a positive electrode based on such redox reactions involved mainly by bromide. Furthermore, a hybrid capacitor with a lithium metal anode and a lithium-ion battery with a graphite anode were proposed by combining bromine redox-based positive. Optimum electrolytes were investigated for the various cell systems. We have also developed reversible battery systems with a magnesium metal anode with bromide-based electrolytes. We attempt to apply such novel magnesium-bromine systems to usual, closed rechargeable magnesium batteries as well as magnesium air batteries. Our new projects will focus on these novel systems.
|
Free Research Field |
電気化学、特に二次電池およびキャパシタの材料化学
|