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2016 Fiscal Year Final Research Report

Evidence for the existence of the second critical point in tin tetraiodide

Research Project

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Project/Area Number 26400398
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Mathematical physics/Fundamental condensed matter physics
Research InstitutionEhime University

Principal Investigator

FUCHIZAKI KAZUHIRO  愛媛大学, 理工学研究科(理学系), 教授 (10243883)

Project Period (FY) 2014-04-01 – 2017-03-31
Keywordsポリアモルフィズム / ヨウ化錫 / 水 / 第二臨界点 / 相転移
Outline of Final Research Achievements

Various thermodynamic anomalies exhibited by water have recently been considered to be ascribable to the existence of the second critical point at which two waters with different densities are not distinguishable. However, not only the critical point but also the two waters have never been observed. This study, which revealed the existence of the second critical point of tin tetraiodide using in situ synchrotron x-ray absorption measurements, is the world’s first identification. The existence of a region of density maximum in the liquid phase, which supports indirectly the existence of the critical point, was also disclosed.

Free Research Field

物性理論

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Published: 2018-03-22  

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