2016 Fiscal Year Final Research Report
Spectroscopic study on the reactive transition-metal species developed by the discharge-assisted laser ablation method
| Project/Area Number |
26410011
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Shizuoka University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Keywords | 含遷移金属活性種 / 高分解能分光 / レーザーアブレーション / 金属-硫黄間結合 |
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| Outline of Final Research Achievements |
Reactive transition-metal species, which were generated by the discharge-assisted laser ablation method, were observed by Fourier-transform microwave spectroscopy to reveal their physico-chemical properties. We mainly studied on the following species; (1) Gold hydroxide and gold hydrosulfide, (2) Transition metal-bridged sulfur species as the first model for the thiolate-protected transition metal-cluster. For these species, the physico-chemical properties, such as molecular structure and bond character, were explored in detail.
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| Free Research Field |
化学
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