2016 Fiscal Year Final Research Report
Creation of Heterocyclic Compounds Based on Generation of Heavier Group 14 Element Cations and Activation of Small Molecules
| Project/Area Number |
26410035
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Keywords | 合成化学 / 典型元素化学 / 複合材料・物性 / シロール / シリルカチオン / 連鎖反応 / ヒドロシリル化 / ゲルモール |
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| Outline of Final Research Achievements |
Silacyclic compounds were synthesized by the generation of silyl cations from hydrosilanes bearing an aromatic ring and trityl cation, their reactions with alkynes, alkenes, and carbon dioxide, etc., and sequential reactions of formed carbocations with the aromatic ring. π-Extended siloles such as benzosiloles, naphthosiloles, and disiloles, etc. were synthesized by its application to aromatic compounds bearing 1 or 2 sets of alkynyl group and hydrosilyl group at the neighboring position. Furthermore, germa-Friedel-Crafts reaction was developed for the synthesis of dibenzogermoles.
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| Free Research Field |
化学
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