• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2016 Fiscal Year Final Research Report

Development of Novel Synthetic Reactions of Oligosilanes using Transition Metal Complexes

Research Project

  • PDF
Project/Area Number 26410036
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic chemistry
Research InstitutionGunma University

Principal Investigator

Kanno Ken-ichiro  群馬大学, 大学院理工学府, 准教授 (20360951)

Project Period (FY) 2014-04-01 – 2017-03-31
Keywordsオリゴシラン / ヒドロシラン / 遷移金属触媒 / 脱水素カップリング反応 / ヒドロシリル化反応
Outline of Final Research Achievements

Reactions of hydrosilanes using transition metal catalysts are widely known, and various organosilicon compounds can be synthesized. Most of such catalytic reactions, however, could not be used for oligosilane synthesis because most of the transition metals cleave Si-Si bonds. In this study, we have investigated for novel catalytic reactions of hydrooligosilanes without Si-Si bond cleavage. As a result, we found that the alkoxylation reaction and the hydrosilylation reaction of hydrooligosilanes by the ruthenium catalysts proceed without breaking the Si-Si bonds.

Free Research Field

化学

URL: 

Published: 2018-03-22  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi