2015 Fiscal Year Research-status Report
Exploration of facile synthesis for functional porphyrinoids and investigation of their applications
| Project/Area Number |
26410042
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| Research Institution | Nagoya University |
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Principal Investigator |
Shin Jiyoung 名古屋大学, 工学(系)研究科(研究院), 准教授 (30622295)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Keywords | 構造有機化学 / porphyrinoide / organic battery / electrochemistry / bodily / porphyrin |
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| Outline of Annual Research Achievements |
Contracted porphyrinoides were tentatively studied to investigate new function and application-provability. Research on organic batteries continuing undergoes and provides promising results for future publications. Some are reported through an international conference (Pacifichem, Dec. 15~20, Honolulu).
Specific properties of micro-level molecules are tightly connected to the advanced functions of macro-level molecular materials. In recent, single molecular electoproperty on antiaromatic porphyrinoide has been examined to develop those practical application.
On the procedure, antiaromatic porphyrinoide exhibiting distinct chemical reactivity has been examined to interpret the molecular chemical properties and certain results obtained on the corresponding research have been submitted to journals for publication. One of them has been published in the last fiscal year (Angew. Chem. Int. Ed. 2015, 54, 8454-8457; Angew. Chem. 2015, 127, 8574-8577.)
Chemosensing capability was induced to bodipy molecule created with hemi-porphyrin and functionalized to have an ethynyl pyridine which can selectively capture various metal ions. The research has been done in a collaborative research and reported in a journal (J. Photochem. Photobiol. A: Chem. doi:10.1016/j.jphotochem.2015.08.015, In Press, The corrected proof is accessible).
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| Current Status of Research Progress |
Current Status of Research Progress
2: Research has progressed on the whole more than it was originally planned.
Reason
Initial plans for 2015 followed by 2016 have been progressed and some results either were submitted to chemistry journals: Some were published and some are either in press or on preparation.
Most studies in the last fiscal year have aimed on the investigation of practical functional porphyrinoides toward appropriate applications. Several molecular candidates were prepared and their properties were examined. The molecular systems were studied on both micro (individual molecular level) and macro-level properties (intermolecular interaction to show macromolecular properties).
Compared to the earlier fiscal year, schedule adjustment on collaboration and experimental management little bit slower the progress, but smoothly undergoes to obtain promising results.
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| Strategy for Future Research Activity |
The investigation of functional porphyrinoides toward practical applications will be focused continuously. Electrochemical properties on antiaromatic porphyrinodes and electrochemical dynamics on the interconversions of aromatic and antiaromatic systems will be examined. Finally, the applicant will approach to investigate the next generate batteries in both chemical and engineering methods.
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| Causes of Carryover |
Most budget was used for proceeding the research or for attending a conference on this project.
Less than 5000 yen remained as the amount to be used next fiscal year.
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| Expenditure Plan for Carryover Budget |
It was not the enough money for buying a chemical or an experimental tool. It will be combined to the next fiscal year budget and will be used.
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[Presentation] Anti aromatic Norcorrole Batteries2015
Author(s)
Ji-Young Shin, Tetsuya Yamada, Hirofumi Yoshikawa, Kunio Awaga, Hiroshi Shinokubo
Organizer
Pacifichem2015
Place of Presentation
Honolulu, Hawaii, USA
Year and Date
2015-12-15 – 2015-12-20
Int'l Joint Research
