New functional creaction of supramolecular complexes organized between nano-gap metal electrodes

2016 Fiscal Year Final Research Report

• Project/Area Number: 26410070
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Nagoya Institute of Technology
• Principal Investigator: Shiotsuka Michito 名古屋工業大学, 工学(系)研究科(研究院), 准教授 (70293743)
• Co-Investigator(Renkei-kenkyūsha): KAWANISHI YUJI 産業総合研究所, つくば中央第5事業所, 事業所長代理 (80356849)
• Project Period (FY): 2014-04-01 – 2017-03-31
• Keywords: 超分子金属錯体 / ルテニウム錯体 / 白金錯体 / 自己組織化 / 光電子物性 / りん光発光 / 金属ナノ粒子

Outline of Final Research Achievements

The ruthenium(II)-platinum(II) supramolecular complexes linked with diethynyl-phenanthroline and pai extended phenanthroline ligands were synthesized to clarify the photophysical process under the photo-excited state in these supramolecular complexes. Furthermore, the ruthenium(II) complexes with two thiophenol subsituent were linked with two nanometer-gap gold electrode and metal particles of 10 nanometer size. These electrodes were showed unique and complicate current responses.

Free Research Field

錯体化学