中間スピン状態の磁気特性に着目した分子磁性化合物の合成開発

2015 Fiscal Year Research-status Report

• Project/Area Number: 26410080
• Research Institution: Kwansei Gakuin University
• Principal Investigator: 御厨 正博 関西学院大学, 理工学部, 教授 (10157472)
• Project Period (FY): 2014-04-01 – 2017-03-31
• Keywords: 磁気的性質 / スピン状態 / ルテニウム二核錯体 / コバルト錯体 / 鎖状錯体

Outline of Annual Research Achievements

これまで合成した単核金属ユニットや二核金属ユニットの合成例をさらに増やした。そして連結配位子との反応を行い、一次元、二次元、三次元集積化を行った。
二核ルテニウムのジクロロ錯体についてNMRスペクトルに架橋酢酸炭素の異常な高磁場シフトが観測され、ルテニウム二核のスピンが架橋酢酸の炭素原子にまで染み出していることが窺えた。テトラシアニド金酸を連結配位子として用いた場合は二座配位として働き、結果としてcis-, trans-異性体が生じることがX線結晶解析により明らかになった。この異性体はルテニウム二核のカルボキシラトの置換基により変化し、これを検証するために置換基の種類を増やしたものを合成している。連結配位子をテトラシアニド白金酸にすると、２：１型の集積型錯体が得られた。これらの二核ルテニウムのスピン集積型錯体においてはスピン間の磁気的相互作用は弱く反強磁性的なものであった。正八面体型コバルト(II)の単核および二核錯体について八面体型の歪みと磁気異方性との関係を観察するために単結晶の磁化率測定による磁気異方性測定と磁気偏極中性子回折法による磁化密度測定および結晶構造のコバルト(II)の配列から、局所磁化率テンソル法により、磁気異方性のパラメーターを決定した。その結果、単核錯体では磁化容易軸を特定でき、二核錯体では二つのコバルト原子に誘起される磁気モーメントの方向が傾いており、これが磁気的異常性を引き起こしていることがわかった。その他、新たな配位子を用いてバナジウム、銅、ロジウム錯体の合成を行い、結晶構造を明らかにし、これらの配位子が二核や四核錯体を合成できることを確認した。またいくつかの有機配位子について結晶構造を明らかにし、今後の研究展開への布石とした。吸着特性についても検討し、結晶構造との関連性を調べた。

Current Status of Research Progress

2: Research has progressed on the whole more than it was originally planned.

Reason

研究計画に挙げた錯体のうち重要なものは概ね合成でき、磁気的特性を調べることができた。類縁化合物の磁気的性質も調べた。磁気偏極中性子回折法による磁化密度測定および単結晶の磁化率測定および結晶構造解析からコバルト錯体について磁気異方性の具体的観測結果を得た。cis-, trans-異性や２：１型集積など新しい集積構造を見出した。類縁化合物の窒素吸着能測定により、結晶構造との関連性を明らかにし、吸着特性との複合化へのきっかけを得た。

Strategy for Future Research Activity

これまで合成した単核金属ユニットや二核金属ユニット、一次元、二次元、三次元集積の合成例を検証して重要なものや新しい展開を期待できる系についてさらなる合成を行い、磁気異方性がどのように観測されるか検討する。二核ルテニウムの系についても磁気偏局中性子法の適用を検討する。この系の面白い所はNMRスペクトルにおいて架橋酢酸炭素の異常な高磁場シフトが観測される点で、ルテニウム二核のスピンが架橋酢酸の炭素原子にまで染み出していることが窺え、磁気偏極中性子回折法により、これを直接観測できるのではないかと期待される。さらにこれまで手がけた新たな有機配位子の系についても合成を行い、合成例の拡充を図る。併せて錯体の集積構造の空隙構造の有無についても調べ、ガス分子吸着能への可能性、さらに液晶性や電導性についても調べ、磁気異方性との複合物性へ向けた展開を図る。

Research Products

• [Journal Article] Preparation, structure, and dynamic and electrochemical behaviors of dinuclear rhodium(I) complexes with bridging formamidinato ligands (2016)
  • Author(s): Yuki Ide, Takahisa Ikeue, Yusuke Kataoka, Ryoko Inoue, Mikio Nakamura, Daisuke Yoshioka, Masahiro Mikuriya, Tatsuya Kawamoto, Makoto Handa
  • Journal Title: J. Organomet. Chem. Volume: 803 Pages: 92-103
  • DOI: http://dx.doi.org/10.1016/j.organchem.2015.12.08
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Polarized Neutron Diffraction as a Tool for Mapping Molecular Magnetic Anisotropy: Local Susceptibility Tensors in CoII Complexes (2016)
  • Author(s): Karl Rider, Beatrice Gillon, Arsen Gukasov, Gregory Chaboussant, Alain Cousson, Dominique Luneau, Ana Borta, Jean-Francois Jacquot, Ruben Checa, Yukako Chiba, Hiroshi Sakiyama, and Masahiro Mikuriya
  • Journal Title: Chem. Eur. J. Volume: 22 Pages: 724-735
  • DOI: 10.1002/chem.201503400
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Synthesis and Crystal Structure of Potassium Ethylendiaminetetraacetatocobaltate(III) (2016)
  • Author(s): Ryoji MITSUHASHI and Masahiro MIKURIYA
  • Journal Title: X-ray Struct. Anal. Online Volume: 32 Pages: 5-6
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Crystal Structure of a Dinuclear Zinc(II) Complex with a Phenol-based Dinucleating Ligand (2016)
  • Author(s): Misaki ITO, Ryoji MITSUHASHI, Masahiro MIKURIYA, and Hiroshi SAKIYAMA
  • Journal Title: X-ray Struct. Anal. Online Volume: 32 Pages: 13-14
  • Peer Reviewed / Open Access
• [Journal Article] Synthesis and Crystal Structure of a Tetranuclear Oxidovanadium(IV) Complex with 2,6-Bis(hydroxymethyl)-4-methylphenol (2016)
  • Author(s): Masahiro MIKURIYA, Masami FUKUTANI, Masataka OMOTE, Daisuke YOSHIOKA, and Ryoji MITSUHASHI
  • Journal Title: X-ray Struct. Anal. Online Volume: 32 Pages: 15-17
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Double azido-bridged and mixed-bridged binuclear copper(II) and nickel(II) compounds with N,N, O-donor Schiff bases: Synthesis, structure, magnetic and DFT study (2015)
  • Author(s): Partha Pratim Chakrabarty, Sanjib Giri, Dieter Schollmeyer, Hiroshi Sakiyama, Masahiro Mikuriya, Ananda Sarker, Sandip Saha
  • Journal Title: Polyhedron Volume: 89 Pages: 49-54
  • DOI: http://dx.doi.org/10.1016/j.poly.2014.12.033
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Crystal Structure of a Lantern-Type Dirhodium(II) Complex with cis-(2:2) Arrangement of Two Formamidinato and Two Trifluoroacetato Bridges (2015)
  • Author(s): Makoto HANDA, Kazuki TAKAHASHI, Asami INOUE, Takahisa IKEUE, Daisuke YOSHIOKA, and Masahiro MIKURIYA
  • Journal Title: X-ray Struct. Anal. Online Volume: 31 Pages: 31-32
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Synthesis and properties of dinuclear oxidovanadium(IV) complexes with cyclam-based macrocyclic ligands having four Schiff-bse pendant arms (2015)
  • Author(s): Masahiro Mikuriya, Taro Kuriyama, Masataka Omote
  • Journal Title: Advancing Coordination, Bioinorganic and Applied Inorganic Chemistry. THE 50th ANNIVERSARY OF ICCBIC, ed. by M. Melnik, P. Segla, and M. Tatarko, Press of Slovak University of Technology, Bratislava Volume: 2015 Pages: 118-125
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis and Crystal Structures of Dinuclear Dioxidovanadium(V) and Tetranuclear Oxidovanadium(IV) Complexes with 2,6-Bis(hydroxymethyl)-4-methylphenol (2015)
  • Author(s): Masahiro MIKURIYA, Masami FUKUTANI, and Daisuke YOSHIOKA
  • Journal Title: X-ray Struct. Anal. Online Volume: 31 Pages: 33-36
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Unprecedented up-field shift in the 13C NMR spectrumof the carbonyl carbons of the lantern-type dinuclear complex TBA[Ru2(O2CCH3)4Cl2] (TBA+ = tetra(n-butyl)ammonium cation) (2015)
  • Author(s): Yuya Hiraoka, Takahisa Ikeue, Hiroshi Sakiyama, Frederic Guegan, Dominique Luneau, Beatrice Gillon, Ichiro Hiromitsu, Daisuke Yoshiioka, Masahiro Mikuriya, Yusuke Kataoka, and Makoto Handa
  • Journal Title: Dalton Trans. Volume: 44 Pages: 13439-13443
  • DOI: 10.1039/c5dt01680k
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Pseudo-S6 Complex Cations of a Hexakis-N-methylformamide Nickel(II) Complex (2015)
  • Author(s): Hiroshi Sakiyama, Ryoji Mitsuhashi, and Masahiro Mikuriya
  • Journal Title: X-ray Struct. Anal. Online, Volume: 31 Pages: 45-46
  • Peer Reviewed / Open Access
• [Journal Article] Syntheis and Crystal Structure of a Chain Complex of Copper(II) Pivalate and 1,2-Bis(4-pyridyl)ethane in Relation to Adsorption Property for N2 (2015)
  • Author(s): Masahiro Mikuriya, Mari Yano, Naoya Takahashi, Daisuke Yoshioka, Hidekazu Tanaka, and Makoto Handa
  • Journal Title: X-ray Struct. Anal. Online Volume: 31 Pages: 47-48
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] SYNTHESIS, CRYSTAL STRUCTURE, MAGNETIC PROPERTY, AND N2-GAS-ADSORPTION PROPERTY OF CHAIN COMPOUNDS OF DINUCLEAR COPPER(II) PIVALATE WITH N,N’-BIDENTATE LIGANDS (2015)
  • Author(s): Masahiro Mikuriya, Mari Yano, Naoya Takahashi, Daisuke Yoshioka, Hidekazu Tanaka, and Makoto Handa
  • Journal Title: The Proceedings of the 2nd International Porous and Powder Materials Symposium and Exhibition PPM 2015, ed. by Sevgi Kilic Ozdemir, Mehmet Polat, and Metin Tanoglu, Uc Adim Printing House, Izmir Volume: 2015 Pages: 72-76
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] HYDROPHOBIC MICROPORE IN A CHAIN COMPOUND OF DINUCLEAR COPPER(II) BENZOATE WITH PYRAZINE―ADSORPTION PROPERTIES FOR N2, CCl4, H2O, CO2, AND CH3CN (2015)
  • Author(s): Ryoji Nukada, Masahiro Mikuriya, Makoto Handa, and Hiromitsu Naono
  • Journal Title: The Proceedings of the 2nd International Porous and Powder Materials Symposium and Exhibition PPM 2015, ed. by Sevgi Kilic Ozdemir, Mehmet Polat, and Metin Tanoglu, Uc Adim Printing House, Izmir Volume: 2015 Pages: 77-81
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Tetranuclear Nickel(II) and Cobalt(II) Complexes with 3,5-Dimethyl-1-pyrazolylmethanolato and Acetato Bridges Having a Cubane Core (2015)
  • Author(s): Jongwan LIM, Gibeom KIM, Kyungseo DO, Seonghyun LEE, Sanghoon RYU, Daisuke YOSHIOKA, and Masahiro MIKURIYA
  • Journal Title: X-ray Struct. Anal. Online, Volume: 31 Pages: 49-51
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Synthesis and Crystal Structure of 1,3-Bis(5-nitrosalicylidenamino)-2-propanol (2015)
  • Author(s): Masahiro MIKURIYA, Yuko NAKA, and Daisuke YOSHIOKA
  • Journal Title: X-ray Struct. Anal. Online Volume: 31 Pages: 55-56
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONANE (2015)
  • Author(s): Masahiro Mikuriya, Mayu Hamagawa, Natsuki Tomioka, Daisuke Yoshioka, Naoko Uehara, Rika Fujimori, HirokiYamamoto, Yoshinari Ando, Shoichi Hori, Taro Kuriyama, Ryoji Mitsuhashi, and Makoto Handa, Daisuke Yoshioka, Ryoji Mitsuhashi, and Makoto Handa
  • Journal Title: Chem. J. Moldova Volume: 10(2) Pages: 40-47
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] MIXED-METAL COMPLEXES OF RUTHENIUM(II,III) CARBOXYLATE AND TETRACYANIDOPLATINATE(II) (2015)
  • Author(s): Masahiro Mikuriya, Kenta Ono, Shun Kawauchi, Daisuke Yoshioka, Ryoji Mitsuhashi, and Makoto Handa
  • Journal Title: Chem. J. Moldova Volume: 10(2) Pages: 48-53
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Synthesis and Crystal Structure of 1,4,7-Tris(2-mercaptoethyl)-1,4,7-triazacyclononane (2015)
  • Author(s): Masahiro MIKURIYA, Kazufumi MIYOSHI, Shuhei KURANO, Jun TAGUCHI, Takanori KOTERA, and Daisuke YOSHIOKA
  • Journal Title: X-ray Struct. Anal. Online Volume: 31 Pages: 59-60
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Structural characterization of miu1,2- and miu1,3-bridged-squarato 1D metal(II) coordination polymers (2015)
  • Author(s): Franz A. Mautner, Roland C. Fischer, Masahiro Mikuriya, Seiki Tomohara,Lauren M. Deniger, Salah S. Massoud
  • Journal Title: Polyhedron Volume: 102 Pages: 82-87
  • DOI: http://dx.doi.org/10.1016/j.poly.2015.07.073
  • Peer Reviewed / Int'l Joint Research
• [Presentation] Geometrical Isomers and Redox Properties of Ruthenium(II/III) Complexes with 3-hydroxypicolinamide Ligand (2016)
  • Author(s): MITSUHASHI, Ryoji; SUZUKI, Takayoshi; MIKURIYA, Masahiro
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学（京都府京田辺市）
  • Year and Date: 2016-03-25
• [Presentation] ハロゲンを軸位に有するベンズアミジナート架橋ロジウム(II,III)二核錯体の結晶構造と磁気的相互作用 (2016)
  • Author(s): 三上沙紀・片岡祐介・川本達也・御厨正博・半田 真
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学（京都府京田辺市）
  • Year and Date: 2016-03-24
• [Presentation] 酢酸ルテニウム二核に基づくシアニド架橋ルテニウム白金錯体の合成と性質 (2016)
  • Author(s): 御厨正博・河内 峻・小野顕太・三橋了爾・吉成信人・今野 巧・田中 秀和・半田 真
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学（京都府京田辺市）
  • Year and Date: 2016-03-24
• [Presentation] ハロゲン架橋ベンズアミジナートロジウム二核錯体の結晶構造と磁気的相互作用 (2015)
  • Author(s): 三上沙紀・片岡祐介・川本達也・御厨正博・半田 真
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-15
• [Presentation] ホルムアジミナートイオンと酸素化されたシクロオクタジエンを有するロジウム二核錯体の合成と性質 (2015)
  • Author(s): 井手雄紀・池上崇久・吉岡大輔・御厨正博・半田 真
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-15
• [Presentation] カルボン酸ルテニウム(II,III)二核とテトラシアニド金(III)酸の混合金属錯体の合成と性質および結晶構造 (2015)
  • Author(s): 御厨正博・田中佑典・河内 峻・吉岡大輔・田中秀和・半田 真・三橋了爾
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-15
• [Presentation] 非配位N-H結合を有する鉄(III)錯体の合成と水素結合相互作用 (2015)
  • Author(s): 細谷 聡・三橋了爾・鈴木孝義・御厨正博
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-15
• [Presentation] ビスハライドルテニウム(II,III)二核錯体のイオン結晶と構造 (2015)
  • Author(s): 赤木俊文・藤田涼平・田中秀和・久保田岳志・小俣光司・御厨正博・片岡祐介・半田 真
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-15
• [Presentation] Synthesis and Properties of Mononuclear Cobalt(III) Complexes with Schiff-base Ligands with ONO-donor Set (2015)
  • Author(s): Masahiro Mikuriya, Naoyuki Masuda, Yoshihisa Kakuta, Takaya Inui, Daisuke Yoshioka, Ryoji Mitsuhashi
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-14
• [Presentation] Synthesis and properties of dinuclear copper(II) trimethoxybenzoates (2015)
  • Author(s): Masahiro Mikuriya, Chihiro Yamakawa, Daisuke Yoshioka, Makoto Handa, and Ryoji Mitsuhashi
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-14
• [Presentation] Some Cobalt Complexes with N,N’-Bis(2-hydroxy-3,5-dimethylbenzyl)-N,N’-dimethyl-1,2-ethanediamine (2015)
  • Author(s): Masahiro Mikuriya, Miho Kiyohara, Yuki Katayama, Sinbi Inoue, Aki Sakaguchi, Daisuke Yoshioka, Naomi Kawata, Tsutomu Mizuta, Akira Fuyuhiro, Hiroshi Sakiyama, and Ryoji Mitsuhashi
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-14
• [Presentation] Synthesis and magnetic properties of mixed-metal complexes of dinuclear ruthenium(II,III) carboxylate and tetracyanidoplatinate(II) (2015)
  • Author(s): Masahiro Mikuriya, Kenta Ono, Shun Kawauchi, Makoto Handa, and Ryoji Mitsuhashi
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-14
• [Presentation] Structure and redox properties of ruthenium(II/III) complexes with 3-hydroxypicolinamide ligand (2015)
  • Author(s): Ryoji Mitsuhashi, Takayoshi Suzuki, Masahiro Mikuriya
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-14
• [Presentation] 1,3-ビス(5-ブロモ-3-メトキシサリチリデンアミノ)-2-プロパノールの新規八核マンガン錯体の合成と性質および結晶構造 (2015)
  • Author(s): 御厨正博・友原正揮・倉橋悟志・吉岡大輔・河田尚美・水田 勉・三橋了爾
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-14
• [Presentation] 2,6-ビス(ヒドロキシメチル)-4-メチルフェノールのオキシドバナジウム錯体の合成と性質および結晶構造 (2015)
  • Author(s): 御厨正博・福谷正実・表 正高・吉岡大輔・三橋了爾
  • Organizer: 2015年日本化学会中国四国支部大会
  • Place of Presentation: 岡山大学（岡山県岡山市）
  • Year and Date: 2015-11-14
• [Presentation] SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONADECANE (2015)
  • Author(s): Masahiro Mikuriya, Mayu Hamagawa, Natsuki Tomioka, Daisuke Yoshioka, Naoko Uehara, Rika Fujimori, Hiroki Yamamoto, Yoshinari Ando, Shoichi Hori, Taro Kuriyama, Ryoji Mitsuhashi, and Makoto Handa
  • Organizer: The XVIII-th International Conference "Physical Methods in Coordination and Supramolecular Chemistry"
  • Place of Presentation: Chisinau, Moldova
  • Year and Date: 2015-10-09
  • Int'l Joint Research
• [Presentation] MIXED-METAL COMPLEXES OF DINUCLEAR RUTHENIUM(II,III) CARBOXYLATE AND TETRACYANIDOPLATINATE(II) (2015)
  • Author(s): Masahiro Mikuriya, Kenta Ono, Shun Kawauchi, Daisuke Yoshika, Ryoji Mitsuhashi, and Makoto Handa
  • Organizer: The XVIII-th International Conference "Physical Methods in Coordination and Supramolecular Chemistry"
  • Place of Presentation: Chisinau, Moldova
  • Year and Date: 2015-10-09
  • Int'l Joint Research
• [Presentation] SYNTHESIS, CRYSTAL STRUCTURE AND PROPERTIES OF IRON(III) COMPLEX WITH 2-(2-IMIDAZOLYL)PHENOLATE LIGAND (2015)
  • Author(s): Ryoji Mitsuhashi, Satoshi Hosoya, Takayoshi Suzuki, and Masahiro Mikuriya
  • Organizer: The XVIII-th International Conference "Physical Methods in Coordination and Supramolecular Chemistry"
  • Place of Presentation: Chisinau, Moldova
  • Year and Date: 2015-10-09
  • Int'l Joint Research
• [Presentation] ホルムアジミナートイオンを分子内架橋配位子とするロジウム二核錯体の電気化学的性質および動的挙動における研究 (2015)
  • Author(s): 井手雄紀・池上崇久・片岡祐介・中村幹夫・吉岡大輔・御厨正博・川本達也・半田 真
  • Organizer: 第26回基礎有機化学討論会
  • Place of Presentation: 愛媛大学（愛媛県松山市）
  • Year and Date: 2015-09-25
• [Presentation] ランタン型ルテニウム(II,III)二核錯体の構造と磁気的性質およびスピン分布 (2015)
  • Author(s): 池上崇久・平岡勇哉・中村幹夫・御厨正博・吉岡大輔・片岡祐介・広光一郎・半田 真
  • Organizer: 錯体化学会第65回討論会
  • Place of Presentation: 奈良女子大学（奈良県奈良市）
  • Year and Date: 2015-09-22
• [Presentation] フェノキソ架橋二核コバルト(II)錯体の合成と性質 (2015)
  • Author(s): 崎山博史・菅原恭平・板垣慶愛・吉岡大輔・中優子・御厨正博
  • Organizer: 錯体化学会第65回討論会
  • Place of Presentation: 奈良女子大学（奈良県奈良市）
  • Year and Date: 2015-09-21
• [Presentation] ホルムアジミナートイオンを架橋配位子とするロジウム二核錯体の構造および動的挙動における研究 (2015)
  • Author(s): 井手雄紀・池上崇久・片岡祐介・中村幹夫・吉岡大輔・御厨正博・川本達也・半田 真
  • Organizer: 錯体化学会第65回討論会
  • Place of Presentation: 奈良女子大学（奈良県奈良市）
  • Year and Date: 2015-09-21
• [Presentation] ベンズアミジナート架橋ロジウム(II,III)二核錯体の磁気的性質における置換基効果 (2015)
  • Author(s): 三上沙紀・片岡祐介・川本達也・御厨正博・半田真
  • Organizer: 錯体化学会第65回討論会
  • Place of Presentation: 奈良女子大学（奈良県奈良市）
  • Year and Date: 2015-09-21
• [Presentation] HYDROPHOBIC MICROPORE IN A CHAIN COMPOUND OF DINUCLEAR COPPER(II) BENZOATE WITH PYRAZINE―ADSORPTION PROPERTIES FOR N2, CCl4, H2O, CO2, AND CH3CN (2015)
  • Author(s): Ryoji Nukada, Masahiro Mikuriya, Makoto Handa, and Hiromitsu Naono
  • Organizer: The 2nd International Porous and Powder Materials Symposium and Exhibition PPM 2015
  • Place of Presentation: Cesme Izmir, Turky
  • Year and Date: 2015-09-17
  • Int'l Joint Research
• [Presentation] SYNTHESIS, CRYSTAL STRUCTURE, MAGNETIC PROPERTY, AND N2-ADSORPTION PROPERTY OF CHAIN COMPOUNDS OF DINUCLEAR COPPER(II) PIVALATE WITH N,N’-BIDENTATE LIGANDS (2015)
  • Author(s): Masahiro Mikuriya, Mari Yano, Naoya Takahashi, Daisuke Yoshioka, Hidekazu Tanaka, and Makoto Handa
  • Organizer: The 2nd International Porous and Powder Materials Symposium and Exhibition PPM 2015
  • Place of Presentation: Cesme Izmir, Turky
  • Year and Date: 2015-09-16
  • Int'l Joint Research
• [Presentation] Lantern-Tyoe Rhodium(II) Dinuclear Complewxes with Formamidinato and Carboxylato Bridging Ligands (2015)
  • Author(s): Makoto Handa, Takahisa Ikerue, Yusuke Kataoka, Daisuke Yoshioka, and Masahiro Mikuriya
  • Organizer: Third EuCheMS Inorganic Chemistry Conference EICC-3: Chemistry over the horizon
  • Place of Presentation: Wroclaw, Poland
  • Year and Date: 2015-07-01
  • Int'l Joint Research
• [Presentation] Cyanido-bridged Hetero Metal Complexes Based on Dinuclear Ruthenium Carboxylate (2015)
  • Author(s): Masahiro Mikuriya, Makoto Handa
  • Organizer: Third EuCheMS Inorganic Chemistry Conference EICC-3: Chemistry over the horizon
  • Place of Presentation: Wroclaw, Poland
  • Year and Date: 2015-07-01
  • Int'l Joint Research
• [Presentation] Synthesis and properties of dinuclear oxidovanadium(IV) complexes with cyclam-based macrocyclic ligands having four Schiff-base pendant arms (2015)
  • Author(s): M. Mikuriya, T. Kuriyama, M. Omote
  • Organizer: XXV. International Conference on Coordination and Bioinorganic Chemistry
  • Place of Presentation: Smolenice, Slovakia
  • Year and Date: 2015-06-04
  • Int'l Joint Research
• [Presentation] Mononuclear cobalt(III) complexes with N-salicylidene-2-hydroxy-5-bromobenzylamine and N-salicylidene-2-hydroxy-5-chlorobenzylamine (2015)
  • Author(s): M. Mikuriya, N. Masuda, Y. Kakuta, S. Minato, T. Inui, D. Yoshioka
  • Organizer: XXV. International Conference on Coordination and Bioinorganic Chemistry
  • Place of Presentation: Smolenice, Slovakia
  • Year and Date: 2015-06-04
  • Int'l Joint Research
• [Presentation] Nickel(II) complex with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane (2015)
  • Author(s): M. Mikuriya, M. Hamagawa, N. Tomioka, R. Fujimori, D. Yoshioka, S. Hori, T. Kuriyama, H. Sakiyama, M. Handa
  • Organizer: XXV. International Conference on Coordination and Bioinorganic Chemistry
  • Place of Presentation: Smolenice, Slovakia
  • Year and Date: 2015-06-01
  • Int'l Joint Research