2016 Fiscal Year Final Research Report
Synthesis of electron donors containing fluorine atoms aimed to develop organic conducting materials
| Project/Area Number |
26410095
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Ehime University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
MISAKI Yohji 愛媛大学, 大学院理工学研究科, 教授 (90202340)
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| Research Collaborator |
MORI Shigeki
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Keywords | 電気・磁気的機能 / 有機電子材料 / 電子供与体 / 分子性導体 / 超分子化学 / 双極子相互作用 / ハロゲン結合 |
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| Outline of Final Research Achievements |
Electron donors, in which functional groups with fluorine atoms are contained, were successfully synthesized. X-ray structure analysis revealed that the donor with strong F---F halogen bonds adopts planar structure due to effect on the lattice energy. These results demonstrated that the utilization of halogen bonds like F---F interactions strengthens the intermolecular interactions of molecular conductors.
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| Free Research Field |
化学
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