2016 Fiscal Year Final Research Report
Development of High-Dimensional Argentivorous Molecules
| Project/Area Number |
26410100
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Toho University |
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Principal Investigator |
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| Research Collaborator |
IKEDA Mari
KUWAHARA Shunsuke
LEE Shim Sung
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| Project Period (FY) |
2014-04-01 – 2017-03-31
|
| Keywords | サイクレン / 銀食い分子 / 銀イオン / 銀ーパイ相互作用 / アロステリック効果 / 不斉誘起 |
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| Outline of Final Research Achievements |
To develop high-dimensional argentivorous molecules, three kinds of molecules have been prepared. (1) Bis(tetra-armed cyclen)s were prepared, and the thermodynamic parameters of their Ag+ complexes were measured.(2) A mixture system of chiral and achiral argentivorous molecules showed asymmetric inductions.(3) Cyclen-based cylindrical cryptand which has dietyleneoxy linkers showed an allosteric effect.
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| Free Research Field |
有機化学
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