2016 Fiscal Year Final Research Report
Photocatalytic Conversion of Alcohols for Organic Synthesis
| Project/Area Number |
26410115
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
Hiroshi Naka 名古屋大学, 物質科学国際研究センター, 助教 (70431517)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
|
| Keywords | 有機化学 / 光触媒 / アルコール / 有機合成 / アミン / アルデヒド / 半導体光触媒 |
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| Outline of Final Research Achievements |
This work focused on the photocatalytic conversion of alcohols as a key elementary process in selective organic synthesis. We developed several photocatalytic systems that enable the dehydrogenation of aromatic and aliphatic alcohols to the corresponding aldehydes and the N-alkylation of primary or secondary amines to tertiary amines using alcohols as alkylating reagents. Scope and limitation of these reactions were also clarified.
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| Free Research Field |
有機化学
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