Development of New Transformation Reactions Using Unsaturated Molecules Activated by Silicon Substituents

2016 Fiscal Year Final Research Report

• Project/Area Number: 26410119
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Synthetic chemistry
• Research Institution: Kyoto University
• Principal Investigator: Okamoto Kazuhiro 京都大学, 工学研究科, 助教 (30552658)
• Project Period (FY): 2014-04-01 – 2017-03-31
• Keywords: ケイ素置換基 / 環化付加 / Lewis酸 / 超共役 / 選択的有機合成

Outline of Final Research Achievements

In this research, we aimed at the establishment of the new transformation reactions based on understanding the specific features of silicon-containing unsaturated organic molecules by means of the mechanistic and experimental studies on the Lewis acid-catalyzed selective cycloaddition reactions using silicon-containing unsaturated organic molecules. As a result, we have developed some new selective synthetic methods using the effect of silicon substituents. The obtained insights on the effect of silicon substitution towards the synthetic utilities would cause further developments and applications of organic reactions using heteroatom-based unsaturated molecules.

Free Research Field

有機金属化学・有機合成化学