2016 Fiscal Year Final Research Report
Mechanistic Analysis of Chelate Extraction Using a Single Water Microdroplet/oil System by Microchemical Analysis Technique
| Project/Area Number |
26410144
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Analytical chemistry
|
|---|
| Research Institution | University of Tsukuba |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2014-04-01 – 2017-03-31
|
| Keywords | キレート抽出 / 微小液滴 / 顕微分光 / 微小電極 |
|---|
| Outline of Final Research Achievements |
Using a cadmium-deposited microelectrode with a recess (diameter of 20 μm, depth of 10 μm), an electrochemically generated cadmium(II) ion in a water microdroplet injected into the recess by microcapillary manipulation-injection technique was reacted with a 5-octyloxymethyl-8-quinolinol (HC8Q) in 1,6-dichlorohexane. The fluorescence intensity of Cd(C8Q)2 in the vicinity of the water-microdroplet/oil interface was analyzed by a confocal fluorescence microscope. Based on the kinetic analysis of the time dependence of the fluorescence intensity, the rate-determining step of the extraction rate was shown to be Cd(C8Q)+ desorption at the water-microdroplet/oil interface.
|
| Free Research Field |
分析化学
|
