2016 Fiscal Year Final Research Report
Preparation and Characterization of Nes Superconductive Bismuth Oxides by Hydrothermal Reaction
| Project/Area Number |
26420678
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic materials/Physical properties
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| Research Institution | University of Yamanashi |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Keywords | 水熱反応 / 超伝導 / ビスマス酸化物 / 結晶構造 |
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| Outline of Final Research Achievements |
New superconductive bismuth oxides, (K1.00)(Ba1.00)3(Bi0.89Na0.11)4O12, (Ba0.62K0.38)(Bi0.92Mg0.08)O3 and (Ba0.83K0.17)(Bi0.54Pb0.46)O3 were prepared by hydrothermal reaction. The first one had a double perovskite-type structure with Tc = 31.5K and the second and third ones had a simple perovskite-type structure. The Tc of the second and third ones were 30 and 22.8k, respectively. Their crystal structures were refined by Rietveld method using synchrotron X-ray powdewr diffraction data.
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| Free Research Field |
無機合成化学
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