2016 Fiscal Year Final Research Report
Study on the catalyst design of nanocluster and support
| Project/Area Number |
26420784
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Chiba University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Keywords | ナノクラスター / XAFS / 酸化ニッケル触媒 / 酸化鉄触媒 / 担体界面構造 / コロイド / チオフェノールカップリング反応 / アルコール酸化反応 |
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| Outline of Final Research Achievements |
Base metal, such as nickel, nanocluster (NC) catalyst was prepared and applied to the catalyst. The interface structure between the NiO-NC and silica support promoted the NiO-NC catalysis of oxidative thiophenol coupling reaction. Polymer stabilizer, which was employed as a stabilizing ligand to prevent the NC aggregation, itself can block the active site during the catalysis. Polymer stabilizer remained on the support not on NC also showed the stabilizing effect.
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| Free Research Field |
触媒化学
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