2016 Fiscal Year Final Research Report
Development of homogeneous and heterogeneous oxidation catalysts based on molecular design of metal complex active sites
| Project/Area Number |
26420788
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Kanagawa University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
NAKAZAWA JUN 神奈川大学, 工学部, 特別助教 (70550888)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Keywords | 選択酸化触媒 / 錯体触媒 / 固定化錯体触媒 / 過酸化物 / 酸素分子活性化 / ニッケル / 鉄 / コバルト |
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| Outline of Final Research Achievements |
Homogeneous and heterogeneous metallocomplex catalysts active for the oxidation of hydrocarbons were developed. Chelating ligand consisting of oxazoline derivatives were employed to nickel complex catalysts active for alkane oxidation. A mononuclear iron complex exhibiting oxygen molecule activating ability was synthesized by using an imidazole-based bidentate ligand and a tridentate pyrazole based ligand. Immobilized metallocomplex catalysts based on a series of these chelating ligands were synthesized. Regulation of the amount of the organic functional groups which work as a linker between the ligands and the inorganic oxide support resulted in controlling the structures and catalytic activities of the metallocomplex sites.
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| Free Research Field |
錯体化学，触媒化学，生物無機化学
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