2016 Fiscal Year Final Research Report
Syntheses of Cationic Metal Complexes with Z-Ligand and Its Application
| Project/Area Number |
26460004
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Kanazawa University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Keywords | Z型配位子 / 金 / 触媒反応 / 環化反応 / 金属活性化 |
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| Outline of Final Research Achievements |
The Au complexes featuring a Z-type ligand (boron atom) as a σ-acceptor were developed for elucidating the effect of electron withdrawing on catalytic reactions. An cyclization in the presence of either [Au→B]+ or [Au]+ showed that [Au→B]+ promotes the reactivity, which enabled the effective construction of not only five- and six-membered rings, but also seven-membered rings.
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| Free Research Field |
有機化学
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