2015 Fiscal Year Final Research Report
Realization of unprecedented carbon-carbon bond formation based on the stabilization strategy of iodonium species
| Project/Area Number |
26620036
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Ritsumeikan University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Keywords | 新規反応開発 |
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| Outline of Final Research Achievements |
Based on our concept for isolation of reaction intermediate by stabilization with bridged structure, we have succeeded in isolation and structural determination of hypervalent iodonium species, and as an extension of the strategy new synthesis has been developed by utilizing new information of the intermediates in reactivity. In addition, as an extended research theme, we have discovered a new bond-forming reaction by performing generation and use of very unstable iodonium intermediate having sp3 carbon-hypervalent bonds not utilized in synthesis before.
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| Free Research Field |
有機化学
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