2015 Fiscal Year Final Research Report
Preparation of Coordination Polymers from Liquids: Phase Transformation by Heat and Light
| Project/Area Number |
26620046
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kobe University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
KUWAHARA Daisuke 電気通信大学, 研究設備センター, 准教授 (50270468)
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Keywords | イオン液体 / メタロセン / 配位高分子 / 有機金属錯体 / ルテニウム錯体 / 光反応 |
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| Outline of Final Research Achievements |
An ionic liquid has been developed that transforms into an amorphous coordination polymer when exposed to ultraviolet light and returns to liquid form when heated. The solid-liquid transformation is fully reversible. The ionic liquid contains a cationic ruthenium sandwich complex with cyano groups. This study reveals a method that creates coordination polymers by exposing liquids to light.
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| Free Research Field |
物性化学
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