2015 Fiscal Year Final Research Report
Electrochromic Reaction System with Extraordinarly Current Efficiency over 10000%
Project/Area Number |
26620067
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Functional solid state chemistry
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Research Institution | Nara Institute of Science and Technology |
Principal Investigator |
KAWAI TSUYOSHI 奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (40221197)
|
Project Period (FY) |
2014-04-01 – 2016-03-31
|
Keywords | エレクトロクロミズム / 電流効率 / 電気化学反応 / 酸化還元電位 |
Outline of Final Research Achievements |
Novel molecular science was conducted for achieving electrochemical Coulombic efficiency higher than 10000%. Target molecules showed electrochemical oxidative cycloreversion isomerization with ideal zero-order kinetics independent of concentration of substrate. Chemical modification supported systematic stabilization of O+ component and rapid fading isomerization was observed without electrochemical current, indicating Coulombic efficiency higher than 10000%.
|
Free Research Field |
機能材料科学
|