2015 Fiscal Year Final Research Report
Development of Folded pi-Stacking Polymers and their Ability of Singlet Fission
| Project/Area Number |
26620109
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Kanagawa University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Keywords | 機能性高分子 / 一重項分裂 / 積層高分子 / 有機薄膜太陽電池 |
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| Outline of Final Research Achievements |
New tethering units that are more stable thermally and chemically than the previous compounds were developed. Polymers comprised with them were synthesized and it was found that the polymers have H-type stacking conformation. In addition to H-stacking polymers, polymers having structure of J-stacking, staggered stacking and alternatively staking of different pi-units were developed and their optical properties were investigated. New cross-stacking polymers that have pi-units extended to polymer chain vertical axis were developed and they exhibited higher hole-transferring ability than previous folded polymers. Investigation of properties of thin-layer photovoltaic device comprised with folded pi-stacking polymers and ability of singlet-fission in them is underway in our laboratory.
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| Free Research Field |
有機合成化学 合成有機金蔵化学 高分子化学
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