Creation of highly ion-conductive metal-organic frameworks including hydroxide ions by salt-inclusion reaction

2016 Fiscal Year Final Research Report

• Project/Area Number: 26810037
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Inorganic chemistry
• Research Institution: Kyushu University
• Principal Investigator: Sadakiyo Masaaki 九州大学, カーボンニュートラル・エネルギー国際研究所, 助教 (40635885)
• Project Period (FY): 2014-04-01 – 2017-03-31
• Keywords: 配位高分子 / 配位子交換反応 / イオン伝導体 / 水酸化物イオン / 塩包接反応

Outline of Final Research Achievements

We tried to design and to synthesize novel metal-organic frameworks (MOFs) including hydroxide ions inside the pore of MOFs by employing salt-inclusion and ligand exchange reaction. We applied salt-inclusion reaction to thermally stable MOFs and revealed its availability. We also clarify the tolerabiity of various MOFs for strong alkaline condition. We succeeded in synthesizing a novel MOF having basic sites on its framework by applying the ligand exchange reaction to alkaline-stable ZIF-8 as a mother framework.

Free Research Field

無機化学