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2015 Fiscal Year Final Research Report

Evaluation of chemical properties of metallomicelle and its application to aqueous catalytic reaction

Research Project

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Project/Area Number 26810054
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Taira Toshiaki  国立研究開発法人産業技術総合研究所, 化学プロセス研究部門, 研究員 (40711974)

Project Period (FY) 2014-04-01 – 2016-03-31
Keywords触媒 / 界面活性剤 / パラジウム / 水 / 反応場
Outline of Final Research Achievements

A surface-active N-heterocyclic carbene (NHC) ligand having a hydrophilic and hydrophobic parts was synthesized. The NHC and its Pd complex behaved as a general surfactant, and hydrophobic oily substrates were emulsified in water, resulting in the acceleration of the Mizoroki-Heck reaction under heterogeneous conditions. Our results demonstrated that the reactive emulsion interface rendered by the surface-active NHC is effective for the aqueous Mizoroki-Heck reaction.

Free Research Field

化学

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Published: 2017-05-10  

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