2015 Fiscal Year Final Research Report
Development of new catalysts utilizing cationic heterocyclic compounds as electron withdrawing groups
| Project/Area Number |
26810063
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
|
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| Research Institution | Meijo University |
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Principal Investigator |
|
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| Project Period (FY) |
2014-04-01 – 2016-03-31
|
| Keywords | 有機触媒 / ブレンステッド酸 / Diels-Alder反応 / 不斉合成 |
|---|
| Outline of Final Research Achievements |
Chiral pyridinium phosphoramide was designed and synthesized to be a dual acid catalyst in which both the pyridinium proton and the adjacent imide-like proton activated by the cationic pyridinium moiety could work cooperatively as strong dual proton donors. The dual acid catalyst was successfully used for the asymmetric cycloaddition reaction between 1-amidedienes and maleimides to afford a variety of compounds in highly stereoselective manners.
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| Free Research Field |
有機化学
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